| |
|
 |
Research Projects
Prof. Adriano Lisboa Monteiro
The research focuses on homogeneous catalysis with a strong
emphasis on metal-mediated synthetic methodologies for
the construction of C-C bonds (cross-coupling reactions,
carbonylation, hydrogenation and oligomerisation). Our
main goals are:
- development of simple and efficient Pd and Ni-catalytic
system operating at low catalyst loading and under mild
conditions.
- design of new catalyst and ligands.
- catalyst recovering and reutilization.
- mechanistic studies.
- application in the synthesis of fine chemicals.
Selected References
1. Nunes, C.M.; Limberger, J.; Poersch,
S.; Seferin, M.; Monteiro, A.L.; trans-Stilbene as a starting
material for the synthesis of tamoxifen based on Pd-catalyzed
cross-coupling reactions. Synthesis 2009, in press.
2. Zim, D.; Nobre, S. M.; Monteiro, A.
L. J. Mol. Catal. A: Chem. 2008, 287, 16. Suzuki cross-coupling
reaction catalyzed by sulfur-containing palladacycles:
Formation of palladium active species
3. Nobre, S. M.; Wolke, S. I.; da Rosa,
R. G.; Monteiro, A. L. Tetrahedron Lett. 2004, 45, 6527.
Simple and efficient protocol for catalyst recycling and
product recovery in the Pd-catalyzed homogeneous Suzuki
reaction.
4. Zim, D.; Lando, V. R.; Dupont, J.;
Monteiro, A. L. Org. Lett. 2001, 3, 3049NiCl2(PCy3)2:
A simple and efficient catalyst precursor for the Suzuki
cross-coupling of aryl tosylates and arylboronic acids
5. Fassina, V.; Ramminger, C.; Seferin,
M.; Monteiro, A. L. Tetrahedron 2000, 56, 7403. Nickel
catalyzed hydrovinylation of arylethylenes: General method
of synthesis of alpha-arylpropionic acids intermediates
6. Lando, V. R.; Monteiro, A. L. Org.
Lett. 2003, 5, 2891. Simple and efficient protocol for
the synthesis of functionalized styrenes from 1,2-dibromoethane
and arylboronic acids
7. Silveira, P. B.; Monteiro, A. L. J.
Mol. Catal. A: Chem. 2006, 247, 1. Pd-catalyzed carbonylation
of alpha-arylvinyl bromides: Synthesis of 2-arylacrylic
esters
|
|
|
|
